HILTI HIT-HY150 MAX Chemwatch Independent Material Safety Data Sheet Issue Date: 12-Nov-2012 CHEMWATCH 22-5419 Version No:22.214.171.124 CD 2012/4 Page 1 of 7 Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME HILTI HIT-HY150 MAX PRODUCT USE Adhesive mortar for anchor fastenings in concrete. 2 compoent foil pack contains: Component A: Urethane methacrylate resin, inorganic filler Component B: Dibenzoyl peroxide, phlegmatized. SUPPLIER Company: Hilti (Aust.) Pty Ltd Address: Level 5, 1G Homebush Bay Drive Rhodes NSW, 2138 Australia Telephone: +61 2 8748 1000 Emergency Tel:131 292 (8am to 6pm) Fax: +61 2 8748 1190 Section 2 - HAZARDS IDENTIFICATION STATEMENT OF HAZARDOUS NATURE HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. RISK Risk Codes
• Irritating to eyes, respiratory system and skin.
• May cause SENSITISATION by skin contact.
• Possible risk of irreversible effects. SAFETY Safety Codes
• Wear suitable protective clothing.
• To clean the floor and all objects contaminated by this material, use waterand detergent.
• Keep away from food, drink and animal feeding stuffs.
• In case of contact with eyes, rinse with plenty of water and contact Doctor orPoisons Information Centre.
• If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (showthis container or label). Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
other ingredients determined not to be hazardous
continued. HILTI HIT-HY150 MAX Chemwatch Independent Material Safety Data Sheet Issue Date: 12-Nov-2012 CHEMWATCH 22-5419 Version No:126.96.36.199 CD 2012/4 Page 2 of 7 Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS Section 4 - FIRST AID MEASURES SWALLOWED • Immediately give a glass of water. • First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. EYE ■ If this product comes in contact with the eyes: • Wash out immediately with fresh running water. • Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. • Seek medical attention without delay; if pain persists or recurs seek medical attention. • Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. SKIN ■ If skin contact occurs: • Immediately remove all contaminated clothing, including footwear. • Flush skin and hair with running water (and soap if available). • Seek medical attention in event of irritation. INHALED • If fumes or combustion products are inhaled remove from contaminated area. • Lay patient down. Keep warm and rested. • Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. • Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. NOTES TO PHYSICIAN ■ Treat symptomatically. Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA • Foam. • Dry chemical powder. • BCF (where regulations permit). • Carbon dioxide. FIRE FIGHTING • Alert Fire Brigade and tell them location and nature of hazard. • Wear breathing apparatus plus protective gloves. • Prevent, by any means available, spillage from entering drains or water courses. • Use water delivered as a fine spray to control fire and cool adjacent area. FIRE/EXPLOSION HAZARD • Combustible. • Slight fire hazard when exposed to heat or flame. • Heating may cause expansion or decomposition leading to violent rupture of containers. • On combustion, may emit toxic fumes of carbon monoxide (CO). Combustion products include: carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of burning organic material. • Benzoyl peroxide decomposes when heated with formation of dense white toxic smoke of benzoic acid, phenyl benzoate, terphenyls,
May emit poisonous fumes. May emit corrosive fumes. FIRE INCOMPATIBILITY • Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may HAZCHEM None continued. HILTI HIT-HY150 MAX Chemwatch Independent Material Safety Data Sheet Issue Date: 12-Nov-2012 CHEMWATCH 22-5419 Version No:188.8.131.52 CD 2012/4 Page 3 of 7 Section 6 - ACCIDENTAL RELEASE MEASURES MINOR SPILLS • Clean up all spills immediately. • Avoid contact with skin and eyes. • Wear impervious gloves and safety goggles. • Trowel up/scrape up. MAJOR SPILLS ■ Minor hazard. • Clear area of personnel. • Alert Fire Brigade and tell them location and nature of hazard. • Control personal contact with the substance, by using protective equipment as required. • Prevent spillage from entering drains or water ways. Personal Protective Equipment advice is contained in Section 8 of the MSDS. Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING • Avoid all personal contact, including inhalation. • Wear protective clothing when risk of exposure occurs. • Use in a well-ventilated area. • Prevent concentration in hollows and sumps. SUITABLE CONTAINER • Metal can or drum • Packaging as recommended by manufacturer. • Check all containers are clearly labelled and free from leaks. STORAGE INCOMPATIBILITY ■ For benzoyl peroxide: • Avoid reaction with acids, alkalis, oxidising and reducing agents, metals and metal oxides, and combustible materials. • Amines and solutions of cobalt salts used as promoters and accelerators in polyester compounds if mixed with benzoyl peroxide will cause spontaneous decomposition (detonation). • Alkalis cause rapid decomposition of benzoyl peroxide with generation of large volumes of carbon dioxide gas (CO2) and may pressurise containers. • Avoid contact with copper, brass, lead and zinc. • Avoid reaction with oxidising agents. STORAGE REQUIREMENTS • Store in original containers. • Keep containers securely sealed. • Store in a cool, dry, well-ventilated area. • Store away from incompatible materials and foodstuff containers. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS Source
The following materials had no OELs on our records• 2- hydroxypropyl
CAS:923- 26- 2 CAS:27813- 02- 1 CAS:122413- 04- 1 CAS:124742- 02- 5
CAS:138258- 23- 8 CAS:191411- 56- 0 CAS:204013- 27- 4 CAS:27072- 46- 4CAS:30348- 68- 6 CAS:32073- 20- 4 CAS:50851- 93- 9 CAS:50975- 16- 1CAS:51424- 40- 9 CAS:51480- 40- 1 CAS:63625- 57- 0 CAS:99609- 88- 8
continued. HILTI HIT-HY150 MAX Chemwatch Independent Material Safety Data Sheet Issue Date: 12-Nov-2012 CHEMWATCH 22-5419 Version No:184.108.40.206 CD 2012/4 Page 4 of 7 Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION MATERIAL DATA 2-HYDROXYPROPYL METHACRYLATE: TRIMETHYLOLPROPANE TRIMETHACRYLATE:
■ For 4-methoxyphenol (MEHQ)MEHQ has caused ocular toxicity in animals and skin depigmentation in rodents and workers. The recommendation for the TLV-TWA
arises from documented eye and skin toxicities and by analogy with hydroquinone.
■ None assigned. Refer to individual constituents.
■ No exposure limits set by NOHSC or ACGIH. CEL TWA: 1 mg/m3 [compare WEEL-TWA* for multifunctional acrylates (MFAs)](CEL = Chemwatch Exposure Limit)Exposure to MFAs has been reported to cause contact dermatitis in humans and serious eye injury in laboratory animals.
Exposure to some MFA-resin containing aerosols has also been reported to cause dermatitis.
■ For benzoyl peroxide:The recommendation for the TLV-TWA is based on the absence of subjective symptoms of irritation of the nose and throat in
humans exposed to 5.25 mg/m3. Whether this is sufficiently low to prevent cumulative effects in man is not known. PERSONAL PROTECTION RESPIRATOR •Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) EYE • Safety glasses with side shields. • Chemical goggles. • Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,
describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include areview of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical andfirst-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event ofchemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed atthe first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washedhands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent]. HANDS/FEET • Wear chemical protective gloves, e.g. PVC. • Wear safety footwear or safety gumboots, e.g. Rubber. NOTE: • The material may produce skin sensitisation in predisposed individuals. Care must be taken, when removing gloves and other
protective equipment, to avoid all possible skin contact.
• Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed. OTHER • Overalls. • P.V.C. apron. • Barrier cream. • Skin cleansing cream. ENGINEERING CONTROLS ■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. continued. HILTI HIT-HY150 MAX Chemwatch Independent Material Safety Data Sheet Issue Date: 12-Nov-2012 CHEMWATCH 22-5419 Version No:220.127.116.11 CD 2012/4 Page 5 of 7 Section 9 - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Grey paste with an ester-like odour; does not mix with water. PHYSICAL PROPERTIES Does not mix with water. Section 10 - STABILITY AND REACTIVITY CONDITIONS CONTRIBUTING TO INSTABILITY ■ Product is considered stable and hazardous polymerisation will not occur. For incompatible materials - refer to Section 7 - Handling and Storage. Section 11 - TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS ACUTE HEALTH EFFECTS SWALLOWED ■ The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence. The material may still be damaging to the health of the individual, following ingestion, especially where pre-existing organ (eg. liver, kidney) damage is evident. Present definitions of harmful or toxic substances are generally based on doses producing mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal tract discomfort may produce nausea and vomiting. In an occupational setting however, ingestion of insignificant quantities is not thought to be cause for concern. EYE ■ This material can cause eye irritation and damage in some persons. SKIN ■ This material can cause inflammation of the skin oncontact in some persons. The material may accentuate any pre-existing dermatitis condition. Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions. Open cuts, abraded or irritated skin should not be exposed to this material. Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. INHALED ■ The material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage. CHRONIC HEALTH EFFECTS ■ Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic problems. Strong evidence exists that this substance may cause irreversible mutations (though not lethal) even following a single exposure. Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population. Laboratory (in vitro) and animal studies show, exposure to the material may result in a possible risk of irreversible effects, with the possibility of producing mutation. Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. continued. HILTI HIT-HY150 MAX Chemwatch Independent Material Safety Data Sheet Issue Date: 12-Nov-2012 CHEMWATCH 22-5419 Version No:18.104.22.168 CD 2012/4 Page 6 of 7 Section 11 - TOXICOLOGICAL INFORMATION
There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some persons compared tothe general population. Prolonged or repeated skin contact with benzoyl peroxide may result in allergic skin reactions even at diluted concentrations. Ingestion results in abdominal pain, low body oxygen and severe depression. Chronic effects of exposure include allergicreactions characterised by redness, itching, oozing, crusting, and scaling of the skin and asthmatic wheezing. Although it doesnot exhibit complete carcinogenic or tumour-initiating activity, it has been associated with certain tumours of like papillomasand squamous cell carcinomas. There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment. Sensitisation may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitised persons should not beallowed to work in situations where exposure may occur. TOXICITY AND IRRITATION ■ Not available. Refer to individual constituents. CARCINOGEN dibenzoyl peroxide
International Agency for Research on Cancer
(IARC) - Agents Reviewed by the IARCMonographs
Section 12 - ECOLOGICAL INFORMATION Ecotoxicity Ingredient Section 13 - DISPOSAL CONSIDERATIONS
• Containers may still present a chemical hazard/ danger when empty. • Return to supplier for reuse/ recycling if possible. Otherwise:• If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill. • Where possible retain label warnings and MSDS and observe all notices pertaining to the product. • Recycle wherever possible or consult manufacturer for recycling options. • Consult State Land Waste Authority for disposal. • Bury or incinerate residue at an approved site. • Recycle containers if possible, or dispose of in an authorised landfill. Section 14 - TRANSPORTATION INFORMATION HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG
Section 15 - REGULATORY INFORMATION Indications of Danger: Xn continued. HILTI HIT-HY150 MAX Chemwatch Independent Material Safety Data Sheet Issue Date: 12-Nov-2012 CHEMWATCH 22-5419 Version No:22.214.171.124 CD 2012/4 Page 7 of 7 Section 15 - REGULATORY INFORMATION REGULATIONS Regulations for ingredients 2-hydroxypropyl methacrylate (CAS: 923-26-2,27813-02-1,122413-04-1,124742-02-5,138258-23-8, 191411-56-0,204013-27-4,27072-46-4,30348-68-6,32073-20-4,50851-93-9,50975-16-1,51424-40-9, 51480-40-1,63625-57-0,99609-88-8) is found on the following regulatory lists; "Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD List of High Production Volume (HPV) Chemicals" trimethylolpropane trimethacrylate (CAS: 3290-92-4) is found on the following regulatory lists; "Australia Inventory of Chemical Substances (AICS)","International Council of Chemical Associations (ICCA) - High Production Volume List","OECD List of High Production Volume (HPV) Chemicals" dibenzoyl peroxide (CAS: 94-36-0) is found on the following regulatory lists; "Australia - South Australia Controlled Substances (Poisons) Regulations - Schedule E: Schedule 2 poisons authorised to be sold by holder of a medicine sellers licence","Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 2","Australia Dangerous Goods Code (ADG Code) - Goods Too Dangerous To Be Transported","Australia Dangerous Goods Code (ADG Code) - List of Currently Assigned Organic Peroxides in Packagings","Australia Exposure Standards","Australia Hazardous Substances","Australia Inventory of Chemical Substances (AICS)", "Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 2","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 4","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","International Agency for Research on Cancer (IARC) - Agents Reviewed by the IARC Monographs","International Air Transport Association (IATA) Dangerous Goods Regulations","International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and Cargo Aircraft","OECD List of High Production Volume (HPV) Chemicals","United Nations Consolidated List of Products Whose Consumption and/or Sale Have Been Banned, Withdrawn, Severely Restricted or Not Approved by Governments" No data for Hilti HIT-HY150 Max (CW: 22-5419) Section 16 - OTHER INFORMATION Denmark Advisory list for selfclassification of dangerous substances Substance INGREDIENTS WITH MULTIPLE CAS NUMBERS Ingredient Name
923- 26- 2, 27813- 02- 1, 122413- 04- 1, 124742- 02- 5, 138258- 23- 8,
191411- 56- 0, 204013- 27- 4, 27072- 46- 4, 30348- 68- 6, 32073- 20- 4,50851- 93- 9, 50975- 16- 1, 51424- 40- 9, 51480- 40- 1, 63625- 57- 0,99609- 88- 8
■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. A list of reference resources used to assist the committee may be found at: www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review orcriticism, as permitted under the Copyright Act, no part may be reproduced by any process without writtenpermission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 12-Nov-2012Print Date: 12-Nov-2012
Educational Technology & Society 4(2) 2001 ICT to Train Students towards Creative Thinking M. Allegra, A. Chifari and S. Ottaviano Institute for Educational and Training Technology Via Ugo La Malfa, 153, 90146 Palermo – Italy email@example.com firstname.lastname@example.org Abstract This study examines the role played by Information Communication Technologies as cognitive
Allegra Maitla und Buaba Verzichtserklärung | Haftungsausschluss Mir ist bewusst, dass meine Teilnahme mit einem gewissen Risiko behaftet ist. Ich bestätige daher ausdrücklich, dass weder der Organisator der Veranstaltung noch die Grischa Alpachallenge Schuld daran tragen, wenn ich mich verletze. Ich befinde mich im Besitz einer gültigen Haftpflichtversicherung und persönlichen Unf