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Anexo I: Programa de eluição do sistema LC 200 de cromatografia líquida. PUC-Rio - Certificação Digital Nº 0710735/CA Anexo II: Curvas de absorvância x concentração dos padrões NiOEP, NiOEP 550 nm
Concentração (Mol L-1)
Figura 6.1: Curva de absorvância x concentração do padrão NiOEP em 550 nm. NiEtioP 550 nm
Concentração (Mol L-1)
Figura 6.2: Curva de absorvância x concentração do padrão NietioP em 550 nm. PUC-Rio - Certificação Digital Nº 0710735/CA VOEP 550 nm
a (
ci 0,02
rvân
so 0,01
Concentração (Mol L-1)
Figura 6.3 : Curva de absorvância x concentração do padrão VOEP em 550 nm NiOEP 570 nm
Concentração (Mol L-1)
Figura 6.4: Curva de absorvância x concentração do padrão NiOEP em 570 nm. NiEtioP 570 nm
cia ( 0,02
rvân
so 0,01
Concentração (Mol L-1)
Figura 6.5: Curva de absorvância x concentração do padrão NiEtioP em 570 nm. PUC-Rio - Certificação Digital Nº 0710735/CA VOEP 570 nm
Concentração (Mol L-1)
Figura 6.6: Curva de absorvância x concentração do padrão VOEP em 570 nm Anexo III: Tabelas com os dados obtidos nos planejamentos Tabela 6.1 Planejamento experimental 2(7-4) com metanol no nebulizador concêntrico. Lente Potência Tº(Isomist) aspiração(rpm) %agua PUC-Rio - Certificação Digital Nº 0710735/CA Tabela 6.2 Otimização de análise com metanol no micronebulizador PFA-100 Tabela 6.3 Planejamento experimental 22 com Tolueno no micronebulizador PFA-100 1350 73675,9 5635.7 35214.1 64380,6 66014,6 1087,4 94,00 52369 3896.8 26050.9 29376,1 43784,4 650 1350 74731,3 4537.5 26666.4 52136,1 44991,1 742,4 47,00 1350 80503,4 5666.4 34175.8 63439,7 72469,6 1113,7 85,70 1350 39357,8 3187.9 21786.4 20925,7 31204 473,3 49,00 1350 54745,9 4077.9 24632.0 32993,8 40410,5 680,4 46,70 1350 40888,6 3532.7 22450.4 21566,6 35114,3 529,7 45,00 50533,8 4747.6 27820.5 31760,4 42330,5 638,7 63,00 1,51 0,15 1350 61399,6 4616.8 30345.2 43722,2 52644,5 839,7 85,30 1350 39472,3 3369.0 22306.3 19911,5 32062,1 453 33,30 PUC-Rio - Certificação Digital Nº 0710735/CA
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