MATERIAL SAFETY DATA SHEET For Chemical Emergency, Spill, Leaf, Fire, Exposure, or Accident, Call CHEMTREC Day or Night: 1-800-424-9300 For Medical Emergencies Only, Call: 1-877-325-1840
Voluntary Purchasing Groups, Inc. American Brand® Permethrin Bonham, Texas 75418
Granules PRODUCT AND COMPANY IDENTIFICATION: PRODUCT: American Brand® Permethrin Granules EPA No.: 55431-4-7401 COMPANY IDENTIFICATION:
2. INGREDIENTS:
(3-phenoxyphenyl) methyl-cis, trans-3-(2,2-dichloroethyenyl) -2,2 dimethylcyclopropanecarboxylate)
3. PHYSICAL FIRST AID MEASURES: IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first five minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. FIRE AND EXPLOSION HAZARD DATA: Flash Point (Method): Flammable Limits: Extinguishing Media:
Use foam, dry chemical, carbon dioxide, or water spray when fighting fires involving this material.
Fire and Explosion Hazards: Can burn in fire. Irritating and toxic gases may be generated by thermal decomposition or Fire Fighting Equipment:
Self-contained breathing apparatus with full facepiece. Full firefighting turn-out gear (Bunker gear).
MATERIAL SAFETY DATA SHEET For Chemical Emergency, Spill, Leaf, Fire, Exposure, or Accident, Call CHEMTREC Day or Night: 1-800-424-9300 For Medical Emergencies Only, Call: 1-877-325-1840
Voluntary Purchasing Groups, Inc. American Brand® Permethrin Bonham, Texas 75418
Granules
Fire Fighting Instructions:
Evacuate area and fight fire upwind from a safe distance to avoid hazardous vapors and
collect water used to fight fire to prevent
damage due to run off. Foam or dry chemical fire extinguishing systems are preferred to prevent environmental damage from excess water run off.
Hazardous Combustion Products:
Carbon monoxide and/or carbon dioxide. Chlorine and hydrogen chloride may be formed.
STABILITY & REACTIVITY DATA: Stability:
Stable, however may decompose if heated.
Conditions to Avoid: Incompatibility with Other Materials: Hazardous Decomposition Products:
Thermal decomposition may release carbon dioxide, carbon monoxide, sulfur oxides, halogen, halogen acids and possible trace amounts of carbonyl halide.
7. ECOLOGICAL INFORMATION: Environmental Summary:
This product is extremely toxic to fish and aquatic invertebrates. It is moderately toxic to birds, and other wildlife. Do not apply directly to water, or to areas where surface water is present. Do not apply where runoff is likely to occur. Do not contaminate water when disposing of equipment washwaters.
Fish Toxicity (Technical):
96 hour LC50, Rainbow trout – 2.5µg/L
Avian Toxicity (Technical):
Oral LD50, Japanese quail - > 13,500 mg/Kg
Bee Toxicity (Technical): Highly 8. DISPOSAL CONSIDERATIONS:
Dispose of in accordance with applicable Federal, state and local laws and regulations.
Container: Accidental Release Measures:
Clean up spills immediately, observing precautions in Section 8 of this document.
SMALL SPILL: Vacuum or sweep up material and place in a container for reuse or disposal. LARGE SPILL: Same as for a small spill. After removal flush and neutralize contaminated area thoroughly with water and a diluted solution of soda ash or bleach. Pick up wash liquid with absorbent and place in chemical waste container for disposal. This material is
water pollutant and should be prevented from entering sewage and drainage systems
HANDLING & STORAGE: Handling: Storage:
Store product in its original labeled container in a cool, dry locked place out of reach of children.
HEALTH HAZARD DATA: MATERIAL SAFETY DATA SHEET For Chemical Emergency, Spill, Leaf, Fire, Exposure, or Accident, Call CHEMTREC Day or Night: 1-800-424-9300 For Medical Emergencies Only, Call: 1-877-325-1840
Voluntary Purchasing Groups, Inc. American Brand® Permethrin Bonham, Texas 75418
Granules
Emergency Overview:
Light brown granules. Avoid breathing dust. Avoid contact with eyes. Keep out of reach of children.
Potential Health Hazards:
May cause skin irritation, numbing, burning and tingling.
Inhalation: Ingestion: Environmental Hazards:
Extremely toxic to fish, other water organisms and bees. Keep out of waterways.
EXPOSURE CONTROLS, PERSONAL PROTECTION: Exposure Limits ( 8-HR TWA): (Refer to Section 7) Engineering Controls:
Ventilation is normally required when handling or using this product to keep exposure to
airborne contaminants below the exposure limit. Facilities storing or utilizing this material
should be equipped with an eyewash facility and a safety shower.
Personal Protective Equipment (PPE): Eye Protection: Safety Clothing:
Long sleeved shirt and long pants. Shoes plus socks.
Gloves: Waterproof Respirator:
When handling in enclosed areas where exposure limits may be exceeded, use a dust/mist filtering respirator (MSHA/NIOSH approval number prefix TC-21C).
Follow manufacture’s instructions for cleaning and maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry. User Safety Recommendations:
Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing.
TOXICOLOGICAL INFORMATION: Acute Toxicity: Oral LD50 Carcinogen Status: OSHA: Mutagenic Data:
Not evidence of effects during in vivo or in vitro studies.
Additional Data:
Not known to exhibit reproductive o birth defects. Repeated or prolonged low level exposure may cause sensitization to subsequent exposures.
TRANSPOT INFORMATION:
Agricultural Insecticide, Solid, N.O.I.B.N.
MATERIAL SAFETY DATA SHEET For Chemical Emergency, Spill, Leaf, Fire, Exposure, or Accident, Call CHEMTREC Day or Night: 1-800-424-9300 For Medical Emergencies Only, Call: 1-877-325-1840
Voluntary Purchasing Groups, Inc. American Brand® Permethrin Bonham, Texas 75418
Granules
DOT Primary/Secondary Label: None required. DOT Primary/Secondary Placard: None
REGULATORY INFORMATION:
All pesticides are governed under the Federal Insecticide, Fungicide, and Rodenticide Act. The regulatory information presented below is pertinent only when this product is handled outside of the normal use and application as a pesticide
OSHA Hazard Communication Standard Status:
CERCLA Reportable Quantity: N/A SARA Title III Status: 302 Extremely Hazardous Substance:
The information presented herein is based on available data from reliable sources and is correct to the best of our knowledge. Voluntary Purchasing Groups, Inc. makes no warranty, express or implied, regarding the accuracy of the data or the results obtained from the use of this product. Nothing herein may be construed as recommending any practice or any product in violation of any lawn or regulations. The user is solely responsible for determining the suitability of any material or product for a specific purpose and for adopting any appropriate safety precautions. We disclaim all liability for injury or damage stemming from any improper use of the material or product described herein.
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